Ebook: Plastics from Bacteria: Natural Functions and Applications

Due to the possibility that petroleum supplies will be exhausted in the next decades to come, more and more attention has been paid to the production of bacterial pl- tics including polyhydroxyalkanoates (PHA), polylactic acid (PLA), poly(butylene succinate) (PBS), biopolyethylene (PE), poly(trimethylene terephthalate) (PTT), and poly(p-phenylene) (PPP). These are well-studied polymers containing at least one monomer synthesized via bacterial transformation. Among them, PHA, PLA and PBS are well known for their biodegradability, whereas PE, PTT and PPP are probably less biodegradable or are less studied in terms of their biodegradability. Over the past years, their properties and appli- tions have been studied in detail and products have been developed. Physical and chemical modifications to reduce their cost or to improve their properties have been conducted. PHA is the only biopolyester family completely synthesized by biological means. They have been investigated by microbiologists, molecular biologists, b- chemists, chemical engineers, chemists, polymer experts, and medical researchers for many years. PHA applications as bioplastics, fine chemicals, implant biomate- als, medicines, and biofuels have been developed. Companies have been est- lished for or involved in PHA related R&D as well as large scale production. It has become clear that PHA and its related technologies form an industrial value chain in fermentation, materials, feeds, and energy to medical fields.

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The investigation and development of plastics synthesized by bacteria is receiving great attention also due to the raising petroleum prices and many environmental concerns related to plastic pollution. Recent results and studies of the properties and various applications of bio-based plastics are presented in this volume. Polyhydroxyalkanoates (PHAs), a biodegradable compound, is treated in several chapters: PHAs as energy and intracellular carbon storage compounds, the metabolic engineering of PHA producers, the development of tailor-made PHAs including uncommon monomers, microbial PHA production from waste raw materials, PHA polyesters produced by both wild-type and recombinant bacteria and the production of medium-chain-length PHAs in pseudomonads. Further microbial plastics discussed are lactic acid and its polymer polylactic acid (PLA), succinic acid and its polymer polybutylene succinate (PBS), ethylene from ethanol and its polymer polyethylene, 1,3-propandiol as well as poly(p-phenylene) (PPP).

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The investigation and development of plastics synthesized by bacteria is receiving great attention also due to the raising petroleum prices and many environmental concerns related to plastic pollution. Recent results and studies of the properties and various applications of bio-based plastics are presented in this volume. Polyhydroxyalkanoates (PHAs), a biodegradable compound, is treated in several chapters: PHAs as energy and intracellular carbon storage compounds, the metabolic engineering of PHA producers, the development of tailor-made PHAs including uncommon monomers, microbial PHA production from waste raw materials, PHA polyesters produced by both wild-type and recombinant bacteria and the production of medium-chain-length PHAs in pseudomonads. Further microbial plastics discussed are lactic acid and its polymer polylactic acid (PLA), succinic acid and its polymer polybutylene succinate (PBS), ethylene from ethanol and its polymer polyethylene, 1,3-propandiol as well as poly(p-phenylene) (PPP).

Content:
Front Matter....Pages i-ix
Introduction of Bacterial Plastics PHA, PLA, PBS, PE, PTT, and PPP....Pages 1-16
Plastics Completely Synthesized by Bacteria: Polyhydroxyalkanoates....Pages 17-37
Natural Functions of Bacterial Polyhydroxyalkanoates....Pages 39-61
Towards Systems Metabolic Engineering of PHA Producers....Pages 63-84
Microbial PHA Production from Waste Raw Materials....Pages 85-119
Industrial Production of PHA....Pages 121-132
Unusual PHA Biosynthesis....Pages 133-186
Metabolic Engineering of Plants for the Synthesis of Polyhydroxyalkanaotes....Pages 187-211
Biosynthesis of Medium-Chain-Length Poly[(R)-3-hydroxyalkanoates]....Pages 213-236
Nodax™ Class PHA Copolymers: Their Properties and Applications....Pages 237-255
Manufacturing of PHA as Fibers....Pages 257-282
Degradation of Natural and Artificial Poly[(R)-3-hydroxyalkanoate]s: From Biodegradation to Hydrolysis....Pages 283-321
Microbial Lactic Acid, Its Polymer Poly(lactic acid), and Their Industrial Applications....Pages 323-346
Microbial Succinic Acid, Its Polymer Poly(butylene succinate), and Applications....Pages 347-388
Microbial Ethanol, Its Polymer Polyethylene, and Applications....Pages 389-404
Microbial 1,3-Propanediol, Its Copolymerization with Terephthalate, and Applications....Pages 405-425
Microbial cis-3,5-Cyclohexadiene-1,2-diol, Its Polymer Poly(p-phenylene), and Applications....Pages 427-446
Back Matter....Pages 447-450

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The investigation and development of plastics synthesized by bacteria is receiving great attention also due to the raising petroleum prices and many environmental concerns related to plastic pollution. Recent results and studies of the properties and various applications of bio-based plastics are presented in this volume. Polyhydroxyalkanoates (PHAs), a biodegradable compound, is treated in several chapters: PHAs as energy and intracellular carbon storage compounds, the metabolic engineering of PHA producers, the development of tailor-made PHAs including uncommon monomers, microbial PHA production from waste raw materials, PHA polyesters produced by both wild-type and recombinant bacteria and the production of medium-chain-length PHAs in pseudomonads. Further microbial plastics discussed are lactic acid and its polymer polylactic acid (PLA), succinic acid and its polymer polybutylene succinate (PBS), ethylene from ethanol and its polymer polyethylene, 1,3-propandiol as well as poly(p-phenylene) (PPP).

Content:
Front Matter....Pages i-ix
Introduction of Bacterial Plastics PHA, PLA, PBS, PE, PTT, and PPP....Pages 1-16
Plastics Completely Synthesized by Bacteria: Polyhydroxyalkanoates....Pages 17-37
Natural Functions of Bacterial Polyhydroxyalkanoates....Pages 39-61
Towards Systems Metabolic Engineering of PHA Producers....Pages 63-84
Microbial PHA Production from Waste Raw Materials....Pages 85-119
Industrial Production of PHA....Pages 121-132
Unusual PHA Biosynthesis....Pages 133-186
Metabolic Engineering of Plants for the Synthesis of Polyhydroxyalkanaotes....Pages 187-211
Biosynthesis of Medium-Chain-Length Poly[(R)-3-hydroxyalkanoates]....Pages 213-236
Nodax™ Class PHA Copolymers: Their Properties and Applications....Pages 237-255
Manufacturing of PHA as Fibers....Pages 257-282
Degradation of Natural and Artificial Poly[(R)-3-hydroxyalkanoate]s: From Biodegradation to Hydrolysis....Pages 283-321
Microbial Lactic Acid, Its Polymer Poly(lactic acid), and Their Industrial Applications....Pages 323-346
Microbial Succinic Acid, Its Polymer Poly(butylene succinate), and Applications....Pages 347-388
Microbial Ethanol, Its Polymer Polyethylene, and Applications....Pages 389-404
Microbial 1,3-Propanediol, Its Copolymerization with Terephthalate, and Applications....Pages 405-425
Microbial cis-3,5-Cyclohexadiene-1,2-diol, Its Polymer Poly(p-phenylene), and Applications....Pages 427-446
Back Matter....Pages 447-450
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