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`...an important aid for anyone involved in mechanistic studies or synthetic work using free radicals. The tables of thermochemical data and the descriptions of the methods used to determine them will enable the reader to quickly gain an appreciation of the factors affecting the quality of such data.'
Angewandte Chemie




Preface. Series Preface. Contributors. Free Radical Reactions; C.Walling. Heats of Formation of Organic Free Radicals by Kinetic Mehods; Wing Tsang. Thermochemical Data for Free Radicals From Studies of Ions; J.C Traeger, B.M. Kompe. Theoretical Studies of the Energetics of Free Radicals; J.S. Francisco, J.A. Montgomery Jr. Photoacoustic Calorimetry of Radicals and Biradicals. J.L. Goodman. A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics; F.J.A.Martinho Simoes, M.E. Minas da Piedade. Resonance and 1,2 Rearrangements in Radicals: From Alkyl Radicals to Alkylcobalamins; A.Greenberg, J.F. Liebman. Solvent Effects in the Reactions of Neutral Free Radicals; J.M. Tanko, N. Kamrudin Suleman. Index.


Preface. Series Preface. Contributors. Free Radical Reactions; C.Walling. Heats of Formation of Organic Free Radicals by Kinetic Mehods; Wing Tsang. Thermochemical Data for Free Radicals From Studies of Ions; J.C Traeger, B.M. Kompe. Theoretical Studies of the Energetics of Free Radicals; J.S. Francisco, J.A. Montgomery Jr. Photoacoustic Calorimetry of Radicals and Biradicals. J.L. Goodman. A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics; F.J.A.Martinho Simoes, M.E. Minas da Piedade. Resonance and 1,2 Rearrangements in Radicals: From Alkyl Radicals to Alkylcobalamins; A.Greenberg, J.F. Liebman. Solvent Effects in the Reactions of Neutral Free Radicals; J.M. Tanko, N. Kamrudin Suleman. Index.
Content:
Front Matter....Pages i-xii
Free Radical Reactions....Pages 1-21
Heats of Formation of Organic Free Radicals by Kinetic Methods....Pages 22-58
Thermochemical Data for Free Radicals from Studies of Ions....Pages 59-109
Theoretical Studies of the Energetics of Radicals....Pages 110-149
Photoacoustic Calorimetry of Radicals and Biradicals....Pages 150-168
A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics....Pages 169-195
Resonance and 1,2-Rearrangement Enthalpies in Radicals: from Alkyl Radicals to Alkylcobalamins....Pages 196-223
Solvent Effects in the Reactions of Neutral Free Radicals....Pages 224-293
Back Matter....Pages 295-301


Preface. Series Preface. Contributors. Free Radical Reactions; C.Walling. Heats of Formation of Organic Free Radicals by Kinetic Mehods; Wing Tsang. Thermochemical Data for Free Radicals From Studies of Ions; J.C Traeger, B.M. Kompe. Theoretical Studies of the Energetics of Free Radicals; J.S. Francisco, J.A. Montgomery Jr. Photoacoustic Calorimetry of Radicals and Biradicals. J.L. Goodman. A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics; F.J.A.Martinho Simoes, M.E. Minas da Piedade. Resonance and 1,2 Rearrangements in Radicals: From Alkyl Radicals to Alkylcobalamins; A.Greenberg, J.F. Liebman. Solvent Effects in the Reactions of Neutral Free Radicals; J.M. Tanko, N. Kamrudin Suleman. Index.
Content:
Front Matter....Pages i-xii
Free Radical Reactions....Pages 1-21
Heats of Formation of Organic Free Radicals by Kinetic Methods....Pages 22-58
Thermochemical Data for Free Radicals from Studies of Ions....Pages 59-109
Theoretical Studies of the Energetics of Radicals....Pages 110-149
Photoacoustic Calorimetry of Radicals and Biradicals....Pages 150-168
A Short and Illustrated Guide to Metal-Alkyl Bonding Energetics....Pages 169-195
Resonance and 1,2-Rearrangement Enthalpies in Radicals: from Alkyl Radicals to Alkylcobalamins....Pages 196-223
Solvent Effects in the Reactions of Neutral Free Radicals....Pages 224-293
Back Matter....Pages 295-301
....
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