Ebook: EPR of Free Radicals in Solids: Trends in Methods and Applications

EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.

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EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.
Content:
Front Matter....Pages i-xvii
Front Matter....Pages 1-1
Continuous Wave EPR of Radicals in Solids....Pages 3-37
Pulsed EPR of Paramagnetic Centers in Solid Phases....Pages 39-93
Dynamical Effects in CW and Pulsed EPR....Pages 95-152
Quantum Effects in Deuterium Labelled Radicals at Low Temperature....Pages 153-195
XSophe — Sophe — XeprView....Pages 197-237
The Calculation of the Hyperfine Coupling Tensors of Biological Radicals....Pages 239-265
AB Initio and Density Functional Calculations of Electronic G-Tensors for Organic Radicals....Pages 267-302
Radiolabelled Radicals Derived from Volatile Organic Compounds (VOCS) Sorbed on Reactive Surfaces....Pages 303-333
Front Matter....Pages 335-335
EPR Studies of Atomic Impurities in Rare Gas Matrices....Pages 337-361
Organic Radical Cations and Neutral Radicals Produced by Radiation in Low-Temperature Matrices....Pages 363-405
Molecule-Based Exchange-Coupled High-Spin Clusters....Pages 407-490
High Spin Molecules Directed Towards Molecular Magnets....Pages 491-528
Electron Transfer and Structure of Plant Photosystem II....Pages 529-563
Recent Development of EPR Dosimetry....Pages 565-599
Optically Detected Magnetic Resonance of Defects in Semiconductors....Pages 601-625
Back Matter....Pages 627-645

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EPR of Free Radicals in Solids: Trends in Methods and Applications presents methods and applications of modern EPR for the study of free radical processes in solids, which so far are only available in the journal literature. The first part of the book, covering trends in methods, contains experimentally oriented chapters on continuous wave and pulsed EPR techniques and special methods involving muon magnetic resonance and optical detection and theory for dynamic studies. New simulation schemes, including the influence of dynamics, are presented as well as advances in the calculation of hyperfine and electronic g-tensors. The second part of the book presents applications involving studies of radiation and photo-induced inorganic and organic radicals in inert matrices, including novel results of quantum effects in small radicals. High-spin molecules and complexes are also considered as well as radical processes in photosynthesis. Recent advances in EPR dosimetry are summarized.
Content:
Front Matter....Pages i-xvii
Front Matter....Pages 1-1
Continuous Wave EPR of Radicals in Solids....Pages 3-37
Pulsed EPR of Paramagnetic Centers in Solid Phases....Pages 39-93
Dynamical Effects in CW and Pulsed EPR....Pages 95-152
Quantum Effects in Deuterium Labelled Radicals at Low Temperature....Pages 153-195
XSophe — Sophe — XeprView....Pages 197-237
The Calculation of the Hyperfine Coupling Tensors of Biological Radicals....Pages 239-265
AB Initio and Density Functional Calculations of Electronic G-Tensors for Organic Radicals....Pages 267-302
Radiolabelled Radicals Derived from Volatile Organic Compounds (VOCS) Sorbed on Reactive Surfaces....Pages 303-333
Front Matter....Pages 335-335
EPR Studies of Atomic Impurities in Rare Gas Matrices....Pages 337-361
Organic Radical Cations and Neutral Radicals Produced by Radiation in Low-Temperature Matrices....Pages 363-405
Molecule-Based Exchange-Coupled High-Spin Clusters....Pages 407-490
High Spin Molecules Directed Towards Molecular Magnets....Pages 491-528
Electron Transfer and Structure of Plant Photosystem II....Pages 529-563
Recent Development of EPR Dosimetry....Pages 565-599
Optically Detected Magnetic Resonance of Defects in Semiconductors....Pages 601-625
Back Matter....Pages 627-645
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