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Materials and Measurements in Molecular Electronics presents new developments in one of the most promising areas of electronics technology for the 21st century. Conjugated polymers, carbon clusters, and many other new molecular materials have been synthesized or discovered in recent years, and some now are on the threshold of commercial application. In the development of molecular materials, detailed knowledge of the structures and electronic states of molecular aggregates is essential. The focus of this book is on the development of new molecular materials and measuring techniques based on modern spectroscopy; included are such topics as Langmuir-Blodgett films, cluster materials, organic conductors, and conjugated electroluminescent polymers.








Content:
Front Matter....Pages I-IX
Front Matter....Pages 1-1
Wide-gap semiconducting materials superior to silicon....Pages 3-18
Front Matter....Pages 19-19
Spectroscopy Methods for Low-Dimensional Systems....Pages 21-35
Time-resolved Spectroscopic Studies of Photoexcited Retinal Isomers in Solution and the Mechanism of Photoisomerization....Pages 36-46
Structure Determination by Using Pulsed ESR....Pages 47-59
Electronic and Chemical Structure of Conjugated Polymer Surfaces and Interfaces: A Review and Some New Results....Pages 60-69
Microscopic and Anisotropic Dynamics of Spin Carriers with/without Charge....Pages 70-84
Optical and Dynamical Properties of One-Dimensional Excitons in Conjugated Polymers....Pages 85-95
Front Matter....Pages 97-97
Langmuir-Blodgett Micro-Sandwiches....Pages 99-111
Control of Electrical and Optical Properties of Langmuir-Blodgett Films Using Photoisomerization of Azobenzene....Pages 112-122
Comparative Study on Langmuir-Blodgett Films and Crystals based on TTF Derivatives with Long Alkyl Chains....Pages 123-136
Front Matter....Pages 137-137
Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)....Pages 139-150
Electronic Properties of Cluster Crystal Incorporated in Zeolite Crystals....Pages 151-162
Conducting fulleride polymers....Pages 163-171
Development of Superconductors based on C60 ....Pages 172-185
Front Matter....Pages 187-187
Optical Properties of Low-Dimensional Molecular Crystals and LB Films....Pages 189-202
?-d interaction in phthalocyanine conductors....Pages 203-216
Low-Dimensional Electronic Systems of Molecular Conductors under High Magnetic Fields....Pages 217-227
Front Matter....Pages 229-229
Electronic Processes Associated with Electroluminescence in Conjugated Polymers....Pages 231-244
Polymer LED Utilizing Poly(arylene vinylenes)....Pages 245-255
Electron-Nuclear Double-Resonance Spectroscopy of Polarons in Conjugated Polymers....Pages 256-267
Back Matter....Pages 269-270



Content:
Front Matter....Pages I-IX
Front Matter....Pages 1-1
Wide-gap semiconducting materials superior to silicon....Pages 3-18
Front Matter....Pages 19-19
Spectroscopy Methods for Low-Dimensional Systems....Pages 21-35
Time-resolved Spectroscopic Studies of Photoexcited Retinal Isomers in Solution and the Mechanism of Photoisomerization....Pages 36-46
Structure Determination by Using Pulsed ESR....Pages 47-59
Electronic and Chemical Structure of Conjugated Polymer Surfaces and Interfaces: A Review and Some New Results....Pages 60-69
Microscopic and Anisotropic Dynamics of Spin Carriers with/without Charge....Pages 70-84
Optical and Dynamical Properties of One-Dimensional Excitons in Conjugated Polymers....Pages 85-95
Front Matter....Pages 97-97
Langmuir-Blodgett Micro-Sandwiches....Pages 99-111
Control of Electrical and Optical Properties of Langmuir-Blodgett Films Using Photoisomerization of Azobenzene....Pages 112-122
Comparative Study on Langmuir-Blodgett Films and Crystals based on TTF Derivatives with Long Alkyl Chains....Pages 123-136
Front Matter....Pages 137-137
Synthesis and Structural Characterization of a Quaternary Zintl Phase Material from the Rb:Ge:In:As System: Rb(Ge1.5ln0.5)As2(As1.5Ge0.5)....Pages 139-150
Electronic Properties of Cluster Crystal Incorporated in Zeolite Crystals....Pages 151-162
Conducting fulleride polymers....Pages 163-171
Development of Superconductors based on C60 ....Pages 172-185
Front Matter....Pages 187-187
Optical Properties of Low-Dimensional Molecular Crystals and LB Films....Pages 189-202
?-d interaction in phthalocyanine conductors....Pages 203-216
Low-Dimensional Electronic Systems of Molecular Conductors under High Magnetic Fields....Pages 217-227
Front Matter....Pages 229-229
Electronic Processes Associated with Electroluminescence in Conjugated Polymers....Pages 231-244
Polymer LED Utilizing Poly(arylene vinylenes)....Pages 245-255
Electron-Nuclear Double-Resonance Spectroscopy of Polarons in Conjugated Polymers....Pages 256-267
Back Matter....Pages 269-270
....
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