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The aim of this book is to familiarize the reader with the practical aspects of polymer analysis. A wealth of practical detail, including some detailed methods is included. The book covers not only the analysis of the main types of polymers and copolymers now in use commercially, but also the analysis of minor non-polymeric components of the polymer formulation, whether they be deliberately added, such as processing additives, or whether they occur adventitiously, such as moisture and residual monomers and solvent. A broad scheme for the examination of polymers is discussed in Chapter 2. Practically all of the major newer analytical techniques and many of the older classical techniques, have been used to examine polymers and their additive systems. As so many different polymers are now used commercially it is also advisable when attempting to identify a polymer to classify it by first separating it into pure polymeric and gross non­ polymeric fractions (Chapter Z) and then carrying out at least a qualitative elemental analysis and possible a quantitative analysis (Chapters 3 and 4) and then in some cases, depending on the elements found, to carry out functional group analysis (Chapters 6 and 9).








Content:
Front Matter....Pages i-xx
Types of Polymers and Their Uses....Pages 1-9
Polymer Characteristics Requiring Elucidation....Pages 10-15
Separation of Polymer and Additives....Pages 16-31
Identification of Polymers....Pages 32-105
Additives, Volatiles and Catalyst Remnants....Pages 106-240
Functional Groups in Polymers....Pages 241-255
Fractionation of Polymers....Pages 256-303
Molecular Weight....Pages 304-321
Copolymer Composition....Pages 322-436
Polymer Microstructure....Pages 437-505
Thermal, Oxidative and Photostability....Pages 506-594
Glass Transition Temperature and Other Transitions....Pages 595-629
Degree of Crystallinity and Melting Temperature....Pages 630-647
Back Matter....Pages 648-822



Content:
Front Matter....Pages i-xx
Types of Polymers and Their Uses....Pages 1-9
Polymer Characteristics Requiring Elucidation....Pages 10-15
Separation of Polymer and Additives....Pages 16-31
Identification of Polymers....Pages 32-105
Additives, Volatiles and Catalyst Remnants....Pages 106-240
Functional Groups in Polymers....Pages 241-255
Fractionation of Polymers....Pages 256-303
Molecular Weight....Pages 304-321
Copolymer Composition....Pages 322-436
Polymer Microstructure....Pages 437-505
Thermal, Oxidative and Photostability....Pages 506-594
Glass Transition Temperature and Other Transitions....Pages 595-629
Degree of Crystallinity and Melting Temperature....Pages 630-647
Back Matter....Pages 648-822
....
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