Ebook: Chemical Physics of Intercalation II

This volume provides a record of the second ASI on the subject "Chemical Physics of Intercalation", which was patterned after its highly successful July 1987 predecessor. A growing community of chemists, physicists and materials scientists has come to appreciate the utility of extending the intercalation concept to generic guest-host compounds and solid solutions. The unifying themes are the complex phase equilibria which result from the competition between repulsive and attractive interactions between and within the guest and host substructures, the tunability of properties by control of guest concentration and superlattice periodicity, and the broad spectrum of potential applications which these materials may provide. The success of this initiative may be judged by noting the enlarged scope of materials covered in this volume as compared to its predecessor. The present volume covers the spectrum from 3-dimensional oxides, 2-dimensional classical layer intercalates,- dimensional doped polymers and zero-dimensional doped fullerene lattices. Hybrid systems such as polymers in layer hosts and nonporous hosts are also treated. Several chapters provide global unifying viewpoints by focussing on sold state chemical aspects, transport and optical properties, the occurrence of superconductivity, etc.

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Content:
Front Matter....Pages i-x
Host Structures Modifications Induced by Intercalation/Deintercalation into Lamellar Chalcogenides....Pages 1-29
Superconducting Intercalation Compounds of C60 and Graphite....Pages 31-61
Conjugated Polymers in Layered Hosts: Formation of Emeraldine Salt and Polyfuran in FeOCl....Pages 63-72
Alkali Metal Compounds of C60: An Intercalation Perspective....Pages 73-92
Staging in Intercalated Graphites, Polymers and Fullerenes....Pages 93-115
Synthesis and Reaction Chemistry of Layered Oxides with Perovskite Related Structures....Pages 117-139
Size-Mismatch Effects in Alloys....Pages 141-159
The Structure, Morphology and Layer Rigidity of Clay Intercalation Compounds....Pages 161-180
Electrochemical Spectroscopy and In-Situ Diffraction Studies of Intercalation Compounds....Pages 181-192
Size-Mismatch Melting in Two Dimensions....Pages 193-196
Tight-Binding Molecular Dynamics for Intercalation Chemistry....Pages 197-200
Quantum Chemical Calculations of C60 Vibrational Frequencies and Electronic States....Pages 201-208
Local Oscillator Model for Superconducting Fullerenes....Pages 209-217
Some Optical Properties of Fullerenes....Pages 219-222
C60 Interaction with GaAs and Bi....Pages 223-226
Photoluminescence of Solid State Fullerenes....Pages 227-231
Electronic Properties of MxC60 as seen by N.M.R. and E.P.R. and Compared to Graphite Intercalation Compounds....Pages 233-238
Magnetic Properties of Alkali Metal Intercalated Fullerides....Pages 239-242
Electrochemical and X-Ray Diffraction Studies of the Li:C60 System....Pages 243-250
Characterization of K-Doped C60 using Positrons....Pages 251-254
Domain Structures in Heavily Alkali-Metal Doped Poly(p-Phenylene Vinylene)....Pages 255-259
Charge Transport and Percolation in Conducting Polymers....Pages 261-264
Synthesis, P and N Doping of Highly Oriented Polyacetylene HOPA....Pages 265-268
Overview on the Chemistry of Intercalation into Graphite of Binary Metallic Alloys....Pages 269-272
Study of FeCl3 and CoCl2 Graphite Intercalation Compounds Reduced by Heavy Alkali Metal Vapour....Pages 273-282
Non — Redox Intercalation into the MPS3 Lamellar Materials: Chemistry and Physical Properties....Pages 283-290
Mineralomimetic Inclusion Behavior of Cadmium Cyanide Systems....Pages 291-298
Modification of the Near Surface Properties of Layered Semiconducting Compounds by Ion Implantation....Pages 299-302
Intercalation by K, Cs, Ba, Pt, Si and C Atoms of the Graphite Monolayer on the Surface of Metals and its Mechanism....Pages 303-310
Optical and Electrical Investigation of Rare Earth Substituted Y1Ba2Cu3O7-? Ceramics and Single Crystals....Pages 311-314
Mercury Intercalation in Titanium and Tantalum Disulfides....Pages 315-324
Li Diffusion in Stage 2 Li-Graphite Intercalation Compounds Studied with Quasielastic Neutron Scattering....Pages 325-332
Electron Transport in Bi2Se3 Intercalated with Hydrazine and Phenyl-Hydrazine....Pages 333-338
Intercalation Complexes of Kaolinite and Ethylenediamine: Structure and Bonds with the Lattice of two Ethylenediamine Conformers....Pages 339-342
Catalytic Oxidation of Sulphide Ions on MoS2 by Intercalation Mechanism....Pages 343-346
Synthesis and Characterization of the First Organosulfur Electron Donor Intercalates of the Metal Dichalcogenides and Dihalides....Pages 347-350
Intercalation of Mercury into 1T-TaS2 and 2H-TaS2: A Combined TDPAC and X-Ray Study....Pages 351-354
Oxidation of Synthetic Annite Mica Characterized by 57Fe Mossbauer Spectroscopy: Hydrogen De-Intercalation and Host-Layer Valence State Populations....Pages 355-359
Specific Heat of the High Tc Organic Superconductor k-(ET)2Cu[N(CN)2]Br....Pages 361-364
Electrical Properties of Oxyethylene Intercalated Compounds....Pages 365-368
Back Matter....Pages 369-373
....Pages 375-378