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Ebook: Reaction Engineering of Step Growth Polymerization

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The literature in polymerization reaction engineering has bloomed sufficiently in the last several years to justify our attempt in putting together this book. Rather than offer a comprehensive treatment of the entire field, thereby duplicating earlier texts as well as some ongoing bookwriting efforts, we decided to narrow down our aim to step growth polymerization systems. This not only provides us the lUxury of a more elaborate presentation within the constraints of production costs, but also enables us to remain on somewhat familiar terrain. The style and format we have selected are those of a textbook. The first six chapters present the principles of step growth polymerization. These are quite general, and can easily be applied in such diverse and emerging fields as polymerization applications in photolithography and microelec­ tronics. A detailed discussion of several important step growth polymeriz­ ations follows in the next five chapters. One could cover the first six chapters of this book in about six to eight weeks of a three-credit graduate course on polymerization reactors, with the other chapters assigned for reading. This could be followed by a discussion of chain-growth and other polymeriz­ ations, with which our material blends well. Alternately, the entire contents of this book could be covered in a course on step growth systems alone.








Content:
Front Matter....Pages i-xiii
Introduction....Pages 1-17
Linear Step Growth Polymerization Following the Equal Reactivity Hypothesis....Pages 19-62
Linear Step Growth Polymerization Violating the Equal Reactivity Hypothesis....Pages 63-91
Nonlinear Step Growth Polymerization....Pages 93-128
Mass Transfer in Step Growth Polymerization....Pages 129-165
Optimal Control of Step Growth Polymerizations....Pages 167-185
Nylon Reactors....Pages 187-239
Polyester Reactors....Pages 241-318
Urethane Polymers and Reaction Injection Molding....Pages 319-363
Epoxy Polymers....Pages 365-385
Polymerization with Formaldehyde....Pages 387-425
Back Matter....Pages 427-430



Content:
Front Matter....Pages i-xiii
Introduction....Pages 1-17
Linear Step Growth Polymerization Following the Equal Reactivity Hypothesis....Pages 19-62
Linear Step Growth Polymerization Violating the Equal Reactivity Hypothesis....Pages 63-91
Nonlinear Step Growth Polymerization....Pages 93-128
Mass Transfer in Step Growth Polymerization....Pages 129-165
Optimal Control of Step Growth Polymerizations....Pages 167-185
Nylon Reactors....Pages 187-239
Polyester Reactors....Pages 241-318
Urethane Polymers and Reaction Injection Molding....Pages 319-363
Epoxy Polymers....Pages 365-385
Polymerization with Formaldehyde....Pages 387-425
Back Matter....Pages 427-430
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