Ebook: Photochemistry and Photophysics of Coordination Compounds

The seventh of a series of prestigeous symposia on the photophysics and photochemistry of coordination compounds in 1987 called scientists from all over the world to the Castle of Elmau in the Bavarian Alps. Well-known researchers met to discuss recent advances in research. This proceedings volume of the 7th ISPPCC collects their contributions and provides an overview of theoretical and chemical aspects in six chapters: - Metal-centered excited states, - Photophysics and photochemistry of Cr(III) complexes, - Excited state properties of tris-2,2'-bipyridine-ruthenium(II) and related complexes, - Photoredox processes, - Organometallic photochemistry, - Methods, applications, and other aspects.

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The seventh of a series of prestigeous symposia on the photophysics and photochemistry of coordination compounds in 1987 called scientists from all over the world to the Castle of Elmau in the Bavarian Alps. Well-known researchers met to discuss recent advances in research. This proceedings volume of the 7th ISPPCC collects their contributions and provides an overview of theoretical and chemical aspects in six chapters: - Metal-centered excited states, - Photophysics and photochemistry of Cr(III) complexes, - Excited state properties of tris-2,2'-bipyridine-ruthenium(II) and related complexes, - Photoredox processes, - Organometallic photochemistry, - Methods, applications, and other aspects.
Content:
Front Matter....Pages I-XI
Front Matter....Pages 1-1
Polarized Luminescence of (Pt(CN)2bipy) Single Crystals-Magnetic Field and Temperature Effects....Pages 3-7
Light-Induced Excited Spin State Trapping in Iron(II) Complexes....Pages 9-15
Infrared Luminescence Spectroscopy of V3+ Doped Cs2NaYX6 (X=C1,Br)....Pages 17-20
Recent Progress in Uranyl Photo-Physics....Pages 21-24
Effects of Macrocyclic and Cryptand Ligands on Photophysics of Eu3+ Ions....Pages 25-28
Front Matter....Pages 29-29
Ligand Field Analysis of the Doublet Excited States in Chromium(III) Trischelated Complexes....Pages 31-34
Quenching of Three Photoaquation Modes of a Chromium(III) Acidoammine....Pages 35-38
Stereochemical Constraints on the Excited State Behavior of Chromium(III)....Pages 39-42
Excited State Behavior as a Probe of Ground-State Ion-Pair Interactions in Chromium(III)-Polypyridyl Complexes....Pages 43-47
Counterion Effects on Doublet Splittings of Chromium(III) Complexes....Pages 49-54
Spectrum-Structure Correlations in Hexacoordinated Transition Metal Complexes....Pages 55-60
Multiphoton-Induced Picosecond Photophysics of Chromium(III)- Polypyridyl Complexes....Pages 61-67
Front Matter....Pages 69-69
On the Orbital Nature of the Luminescent Excited State of Orthometalated Transition Metal Complexes....Pages 71-77
Correlations Between Optical and Electrochemical Properties of RU(II)- Polypyridine Complexes: Influence of the Ligand Structure....Pages 79-83
Broad-Band Emission and Zero-Phonon Lines of Single-Crystal [Ru(bpy)3] (PF6)2 - A Comparison....Pages 85-91
Excited State Behaviors of Ruthenium(II) Complexes as Studied by Time Resolved and Temperature and Solvent Dependent Emission Spectra....Pages 93-100
Front Matter....Pages 101-106
Synthesis and Photophysical Studies of Ortho-Metalated Pd(II) Complexes Including two Novel Pd(II)/Rh(III) Dimers....Pages 107-112
Photoproperties of Ortho-Metalated Ir(III) and Rh(III) Complexes....Pages 113-118
Ground and Excited State Interactions in Multimetal Systems....Pages 119-124
Photophysical and Photochemical Properties of Ruthenium(II) Mixed-Ligand Complexes: Precursors to Homonuclear and Heteronuclear Multimetal Complexes Containing Ruthenium(II), Platinum(II), Rhenium(I) and Rhodium(III)....Pages 69-69
Ground- and Excited-State Acid-Base Equilibria of (2,2’-Bipyridine)Tetracyanoruthenate(II)....Pages 125-128
Front Matter....Pages 129-133
Kinetics and Mechanism of Photochemical Formation of a Pyrazine Bridged Fe(II) Protoporphyrin Polymeric Compound....Pages 135-140
Photoinduced Multielectron Redox Reactions in the (PtC16)2- /Alcohol System: Visible Light Reduction of Platinum Centers....Pages 141-146
Dynamic and Static Outer-Sphere and Inner-Sphere Quenching Processes....Pages 147-150
Photochemistry and Spectroscopy of Ion Pair Charge Transfer Compounds....Pages 151-158
Backward Electron Transfer within Geminate Radical Pair Formed in the Electron Transfer Quenching....Pages 159-164
Photochemistry of Copper Complexes and Its Catalytic Aspects....Pages 165-165
Intramolecular Excited State Electron Transfer from Naphthalene to Cobalt(III)....Pages 167-170
Photochemistry of Coordination Compounds of Main Group Metals. Reductive Elimination of Thallium(III) Complexes....Pages 171-176
Front Matter....Pages 177-180
Photophysics and Photochemistry of Tungsten Carbyne Complexes....Pages 181-184
The Photoisomerization and Photosubstitution Reactions of the Ruthenium Cluster HRu3(Co)10(?-Coch3)....Pages 185-188
Multiple Emission from (?5-C5H5(Re(CO)2L (L = A Substituted Pyridine) Complexes in Room-Temperature Solution....Pages 189-191
Photochemically Induced C-C-Bond Formation in the Coordination Sphere of Transition Metals....Pages 193-196
Front Matter....Pages 197-203
Triplet Quenching by Metal Carbonyls....Pages 205-209
Photoexcitation of W(CO)6 Solutions Containing ?-Diimine Ligands. Kinetics and Mechanism of Chelation for a Series of Photoproduced W(CO)5(?-Diimine) Intermediates....Pages 211-211
Kinetics and Mechanism of C-H Activation Following Photoexcitation of (?5-C5H5) Ir(CO)2 in Hydrocarbon Solutions....Pages 213-216
Identification of H2-, D2-, N2- Bonded Intermediates in the Cr(CO)6 Photocatalyzed Hydrogenation Reactions....Pages 217-220
Spectroscopy and Photochemistry of Ni(CO)2(?-Diimine) Complexes....Pages 221-224
Fe(CO)3(R-DAB), a Complex with Two Close-Lying Reactive Excited States....Pages 225-230
The Photocatalytic Metathesis Reaction of Olefins....Pages 211-211
Photochemical Generation of Nineteen-Electron Organometallic Complexes and their Use as Reducing Agents in Micellar Systems....Pages 231-234
Laser Flash Photolysis of Phosphine-Substituted Dimanganese Carbonyl Compounds....Pages 235-238
Front Matter....Pages 239-242
Electron Trapping in Colloidal TiO2 Photocatalysts: 20 ps to 10 ns Kinetics....Pages 243-246
The Radiation Sensitivity of Select Metal Chelate Polymers: Mechanistic Changes at Higher Energies....Pages 247-252
Temperature Dependent Emission of Copper Porphyrins in Liquid Solution....Pages 253-258
Pressure Effects on Nonradiative Deactivation from Metal Complex Excited States in Solution....Pages 259-262
Heterogeneous Photocatalysis by Metal Sulfide Semiconductors....Pages 263-266
Inorganic Photoinitiators for Photolithographic Applications....Pages 267-270
Photochemical Behaviour of Luminescent Dyes in Sol-Gel and Boric Acid Glasses....Pages 271-274
Industrial Applications of Organometallic Photochemistry....Pages 275-275
Synthesis and Characterization of A ?-oxo-diruthenium Complex as a Precursor to an Efficient Water Oxidation Catalyst....Pages 277-283
The Application of Diffuse Reflectance Laser Flash Photolysis to Metal Phthalocyanines in an Opaque Environment....Pages 285-290
Front Matter....Pages 291-294
Quenching of Singlet Oxygen by Cobalt Complexes....Pages 295-300
Recent Advances in Inorganic and Organometallic Photolithography....Pages 301-306
Back Matter....Pages 307-312
....Pages 313-316