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Detailed study of the rates and mechanisms of combustion reactions has not been in the mainstream of combustion research until the recent recognition that further progress in optimizing burner performance and reducing pollutant emission can only be done with fundamental understanding of combustion chemistry. This has become apparent at a time when our understanding of the chemistry, at least of small-molecule combustion, and our ability to model combustion processes on large computers have developed to the point that real confidence can be placed in the results. This book is an introduction for outsiders or beginners as well as a reference work for people already active in the field. Because the spectrum of combustion scientists ranges from chemists with little computing experience to engineers who have had only one college chemistry course, everything needed to bring all kinds of beginners up to the level of current practice in detailed combustion modeling is included. It was a temptation to include critical discussions of modeling results and computer programs that would enable outsiders to start quickly into problem solving. We elected not to do either, because we feel that the former are better put into the primary research literature and that people who are going to do combustion modeling should either write their own programs or collaborate with experts. The only exception to this is in the thermochemical area, where programs have been included to do routine fitting operations. For reference purposes there are tables of thermochemical, transport-property, and rate­ coefficient data.








Content:
Front Matter....Pages i-xiii
Introduction to Combustion Modeling....Pages 1-19
Computer Modeling of Combustion Reactions in Flowing Systems with Transport....Pages 21-125
Bimolecular Reaction Rate Coefficients....Pages 127-172
Rate Coefficients of Thermal Dissociation, Isomerization, and Recombination Reactions....Pages 173-196
Rate Coefficients in the C/H/O System....Pages 197-360
Survey of Rate Constants in the N/H/O System....Pages 361-421
Modeling....Pages 423-453
Thermochemical Data for Combustion Calculations....Pages 455-473
Back Matter....Pages 475-509



Content:
Front Matter....Pages i-xiii
Introduction to Combustion Modeling....Pages 1-19
Computer Modeling of Combustion Reactions in Flowing Systems with Transport....Pages 21-125
Bimolecular Reaction Rate Coefficients....Pages 127-172
Rate Coefficients of Thermal Dissociation, Isomerization, and Recombination Reactions....Pages 173-196
Rate Coefficients in the C/H/O System....Pages 197-360
Survey of Rate Constants in the N/H/O System....Pages 361-421
Modeling....Pages 423-453
Thermochemical Data for Combustion Calculations....Pages 455-473
Back Matter....Pages 475-509
....
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