Ebook: Semiconductor Nanocrystal Quantum Dots: Synthesis, Assembly, Spectroscopy and Applications

When investigations on semiconductor nanocrystal quantum dots started more than a quarter of a century ago, no one ever believed that nanoparticle research would develop into one of the major fields in modern science. The basis was laid by studies of photocatalysis and artificial water splitting driven by the former oil crisis. These euphorically started activities ebbed away more and more when on one side oil brimmed over again and the scientists on the other did not succeed in the concomitant formation of hydrogen and oxygen. At the same time size quantisation was discovered in nanocrystals initiating a fruitful research field on scaling laws of physical and chemical properties of quantum dots. Especially optical investigations of semiconductor nanocrystals led to fas- nating scientific results and to applications in optoelectronics and biolabeling. Advances in spectroscopic measurements were always correlated with advances in synthesis. The better the size, shape and surface control of the particles was developed, the more detailed and precise was the spectroscopic information - tained. Applications of nanocrystal quantum dots often require asssembly processes for the formation of polymer hybrids or thin films. For this as well as for the use in biomedical applications new ligand chemistry needed to be developed during the recent past. This book gives a very competent view on all these facets of nanocrystal quantum dot research. Twelve chapters are written by experts in the fields in a way introducing the respective concepts and providing comprehensive overview on the current state of the art.

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This is the first book to specifically focus on semiconductor nanocrystals, and address their synthesis and assembly, optical properties and spectroscopy, and potential areas of nanocrystal-based devices. The enormous potential of nanoscience to impact on industrial output is now clear. Over the next two decades, much of the science will transfer into new products and processes.

One emerging area where this challenge will be very successfully met is the field of semiconductor nanocrystals. Also known as colloidal quantum dots, their unique properties have attracted much attention in the last twenty years. These highly efficient fluorophores have a strong band-gap luminescence tuneable by size as a result of the quantum confinement effect. Control over a nanocrystals size at the synthetic stage is a straightforward way to obtain II-VI, III-V and IV-VI binary materials with designed optical properties. Applications of nanocrystals in photonics, optoelectronics and biotechnology are currently envisaged.

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This is the first book to specifically focus on semiconductor nanocrystals, and address their synthesis and assembly, optical properties and spectroscopy, and potential areas of nanocrystal-based devices. The enormous potential of nanoscience to impact on industrial output is now clear. Over the next two decades, much of the science will transfer into new products and processes.

One emerging area where this challenge will be very successfully met is the field of semiconductor nanocrystals. Also known as colloidal quantum dots, their unique properties have attracted much attention in the last twenty years. These highly efficient fluorophores have a strong band-gap luminescence tuneable by size as a result of the quantum confinement effect. Control over a nanocrystals size at the synthetic stage is a straightforward way to obtain II-VI, III-V and IV-VI binary materials with designed optical properties. Applications of nanocrystals in photonics, optoelectronics and biotechnology are currently envisaged.

Content:
Front Matter....Pages I-XI
Growth mechanism, shape and composition control of semiconductor nanocrystals....Pages 1-34
Synthesis of semiconductor nanocrystals in organic solvents....Pages 35-72
Aqueous synthesis of semiconductor nanocrystals....Pages 73-99
Multishell semiconductor nanocrystals....Pages 101-117
Self-assembly of semiconductor nanocrystals into ordered superstructures....Pages 119-169
Semiconductor nanocrystal-polymer composites: using polymers for nanocrystal processing....Pages 171-196
Layer-by-layer (LBL) assembly with semiconductor nanoparticles and nanowires....Pages 197-216
Exciton-phonon interaction in semiconductor nanocrystals....Pages 217-255
Anti-Stokes photoluminescence in semiconductor nanocrystal quantum dots....Pages 257-275
Exciton dynamics and energy transfer processes in semiconductor nanocrystals....Pages 277-310
Fluorescence spectroscopy of single CdSe nanocrystals....Pages 311-347
Applications of quantum dots in biomedicine....Pages 349-365
Back Matter....Pages 367-372

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This is the first book to specifically focus on semiconductor nanocrystals, and address their synthesis and assembly, optical properties and spectroscopy, and potential areas of nanocrystal-based devices. The enormous potential of nanoscience to impact on industrial output is now clear. Over the next two decades, much of the science will transfer into new products and processes.

One emerging area where this challenge will be very successfully met is the field of semiconductor nanocrystals. Also known as colloidal quantum dots, their unique properties have attracted much attention in the last twenty years. These highly efficient fluorophores have a strong band-gap luminescence tuneable by size as a result of the quantum confinement effect. Control over a nanocrystals size at the synthetic stage is a straightforward way to obtain II-VI, III-V and IV-VI binary materials with designed optical properties. Applications of nanocrystals in photonics, optoelectronics and biotechnology are currently envisaged.

Content:
Front Matter....Pages I-XI
Growth mechanism, shape and composition control of semiconductor nanocrystals....Pages 1-34
Synthesis of semiconductor nanocrystals in organic solvents....Pages 35-72
Aqueous synthesis of semiconductor nanocrystals....Pages 73-99
Multishell semiconductor nanocrystals....Pages 101-117
Self-assembly of semiconductor nanocrystals into ordered superstructures....Pages 119-169
Semiconductor nanocrystal-polymer composites: using polymers for nanocrystal processing....Pages 171-196
Layer-by-layer (LBL) assembly with semiconductor nanoparticles and nanowires....Pages 197-216
Exciton-phonon interaction in semiconductor nanocrystals....Pages 217-255
Anti-Stokes photoluminescence in semiconductor nanocrystal quantum dots....Pages 257-275
Exciton dynamics and energy transfer processes in semiconductor nanocrystals....Pages 277-310
Fluorescence spectroscopy of single CdSe nanocrystals....Pages 311-347
Applications of quantum dots in biomedicine....Pages 349-365
Back Matter....Pages 367-372
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