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Hydrogen Bonding – New Insights

Slawomir J. Grabowski

Hydrogen Bonding – New Insights is an extensive text which takes numerous examples from experimental studies and uses these to illustrate theoretical investigations to allow a greater understanding of hydrogen bonding phenomenon. The most important topics in recent studies are considered including:

  • Intra-molecular H-bonds
  • Differences between H-bond and van der Waals interactions from one side and covalent bonds from the other
  • Bader theory to analyze H-bonding
  • Influence of weak H-bonds upon structure and function of biological molecules
  • H-bonds in crystal structures

With contributions from some of the foremost experts in this field this volume provides an invaluable resource for all members of the academic community looking for a comprehensive text on hydrogen bonding. It will be of particular interest to physical and theoretical chemists, spectroscopists, crystallographers and those involved with chemical physics.




Hydrogen Bonding – New Insights

Slawomir J. Grabowski

Hydrogen Bonding – New Insights is an extensive text which takes numerous examples from experimental studies and uses these to illustrate theoretical investigations to allow a greater understanding of hydrogen bonding phenomenon. The most important topics in recent studies are considered including:

  • Intra-molecular H-bonds
  • Differences between H-bond and van der Waals interactions from one side and covalent bonds from the other
  • Bader theory to analyze H-bonding
  • Influence of weak H-bonds upon structure and function of biological molecules
  • H-bonds in crystal structures

With contributions from some of the foremost experts in this field this volume provides an invaluable resource for all members of the academic community looking for a comprehensive text on hydrogen bonding. It will be of particular interest to physical and theoretical chemists, spectroscopists, crystallographers and those involved with chemical physics.




Hydrogen Bonding – New Insights

Slawomir J. Grabowski

Hydrogen Bonding – New Insights is an extensive text which takes numerous examples from experimental studies and uses these to illustrate theoretical investigations to allow a greater understanding of hydrogen bonding phenomenon. The most important topics in recent studies are considered including:

  • Intra-molecular H-bonds
  • Differences between H-bond and van der Waals interactions from one side and covalent bonds from the other
  • Bader theory to analyze H-bonding
  • Influence of weak H-bonds upon structure and function of biological molecules
  • H-bonds in crystal structures

With contributions from some of the foremost experts in this field this volume provides an invaluable resource for all members of the academic community looking for a comprehensive text on hydrogen bonding. It will be of particular interest to physical and theoretical chemists, spectroscopists, crystallographers and those involved with chemical physics.


Content:
Front Matter....Pages i-xx
Characterization of Hydrogen Bonding: From van der Waals Interactions to Covalency....Pages 1-50
Intramolecular Hydrogen Bonds. Methodologies and Strategies for Their Strength Evaluation....Pages 51-107
Changes of Electron Properties in the Formation of Hydrogen Bonds....Pages 109-148
Weak to Strong Hydrogen Bonds....Pages 149-192
The Nature of the C–H· · ·X Intermolecular Interactions in Molecular Crystals. A Theoretical Perspective....Pages 193-244
Weak Hydrogen Bonds Involving Transition Elements....Pages 245-262
Contribution of CH· · ·X Hydrogen Bonds to Biomolecular Structure....Pages 263-292
Neutral Blue-Shifting and Blue-Shifted Hydrogen Bonds....Pages 293-336
Hydrogen–Hydrogen Bonding: The Non-Electrostatic Limit of Closed-Shell Interaction Between Two Hydro....Pages 337-375
Potential Energy Shape for the Proton Motion in Hydrogen Bonds Reflected in Infrared and NMR Spectra....Pages 377-416
Molecular Geometry—Distant Consequences of H-Bonding....Pages 417-439
Topology of X-Ray Charge Density of Hydrogen Bonds....Pages 441-470
Structure–Property Relations for Hydrogen-Bonded Solids....Pages 471-485
Unrevealing the Nature of Hydrogen Bonds: ?-Electron Delocalization Shapes H-Bond Features. Intramolecular and Intermolecular Resonance-Assisted Hydrogen Bonds....Pages 487-512
Back Matter....Pages 513-520


Hydrogen Bonding – New Insights

Slawomir J. Grabowski

Hydrogen Bonding – New Insights is an extensive text which takes numerous examples from experimental studies and uses these to illustrate theoretical investigations to allow a greater understanding of hydrogen bonding phenomenon. The most important topics in recent studies are considered including:

  • Intra-molecular H-bonds
  • Differences between H-bond and van der Waals interactions from one side and covalent bonds from the other
  • Bader theory to analyze H-bonding
  • Influence of weak H-bonds upon structure and function of biological molecules
  • H-bonds in crystal structures

With contributions from some of the foremost experts in this field this volume provides an invaluable resource for all members of the academic community looking for a comprehensive text on hydrogen bonding. It will be of particular interest to physical and theoretical chemists, spectroscopists, crystallographers and those involved with chemical physics.


Content:
Front Matter....Pages i-xx
Characterization of Hydrogen Bonding: From van der Waals Interactions to Covalency....Pages 1-50
Intramolecular Hydrogen Bonds. Methodologies and Strategies for Their Strength Evaluation....Pages 51-107
Changes of Electron Properties in the Formation of Hydrogen Bonds....Pages 109-148
Weak to Strong Hydrogen Bonds....Pages 149-192
The Nature of the C–H· · ·X Intermolecular Interactions in Molecular Crystals. A Theoretical Perspective....Pages 193-244
Weak Hydrogen Bonds Involving Transition Elements....Pages 245-262
Contribution of CH· · ·X Hydrogen Bonds to Biomolecular Structure....Pages 263-292
Neutral Blue-Shifting and Blue-Shifted Hydrogen Bonds....Pages 293-336
Hydrogen–Hydrogen Bonding: The Non-Electrostatic Limit of Closed-Shell Interaction Between Two Hydro....Pages 337-375
Potential Energy Shape for the Proton Motion in Hydrogen Bonds Reflected in Infrared and NMR Spectra....Pages 377-416
Molecular Geometry—Distant Consequences of H-Bonding....Pages 417-439
Topology of X-Ray Charge Density of Hydrogen Bonds....Pages 441-470
Structure–Property Relations for Hydrogen-Bonded Solids....Pages 471-485
Unrevealing the Nature of Hydrogen Bonds: ?-Electron Delocalization Shapes H-Bond Features. Intramolecular and Intermolecular Resonance-Assisted Hydrogen Bonds....Pages 487-512
Back Matter....Pages 513-520
....
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