Ebook: Polyoxometalate Chemistry for Nano-Composite Design

The remarkable range of stoichiometries, structures, and acid-base and redox properties of the polyoxoanions of the early transition metals has lead to their use in areas as diverse as catalysis, imaging, and medicine. Recent progress in polyoxometalate chemistry has opened up the possibility of developing a nanotechnology via a bottom-up approach, starting from molecular (polyoxometalate) subunits which incorporate functionalities that are appropriate for electronic/magnetic devices, and other applications. This book provides an overview of recent progress in polyoxometalate chemistry from leading international research groups. Topics include the formation of large multi-subunit assemblies of polyoxometalates, and their functionalization, magnetic and electron-transfer properties, and biological interactions.

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The remarkable range of stoichiometries, structures, and acid-base and redox properties of the polyoxoanions of the early transition metals has lead to their use in areas as diverse as catalysis, imaging, and medicine. Recent progress in polyoxometalate chemistry has opened up the possibility of developing a nanotechnology via a bottom-up approach, starting from molecular (polyoxometalate) subunits which incorporate functionalities that are appropriate for electronic/magnetic devices, and other applications. This book provides an overview of recent progress in polyoxometalate chemistry from leading international research groups. Topics include the formation of large multi-subunit assemblies of polyoxometalates, and their functionalization, magnetic and electron-transfer properties, and biological interactions.
Content:
Front Matter....Pages i-viii
Chemistry with Nanoparticles: Linking of Ring-and Ball-Shaped Species....Pages 1-15
Prospects for Rational Assembly of Composite Polyoxometalates....Pages 17-26
Composite Materials Derived from Oxovanadium Sulfates....Pages 27-38
Solid State Coordination Chemistry: Bimetallic Organophosphonate Oxide Phases of the M/Cu/O/RPO3 2? Family (M=V, Mo)....Pages 39-57
Polyoxothiomolybdates Derived from the {Mo2O2S2(H2O)6}2+ Building Unit....Pages 59-71
Lanthanide Polyoxometalates: Building Blocks for New Materials....Pages 73-81
Dynamics of Organometallic Oxides: From Synthesis and Reactivity to DFT Calculations....Pages 83-95
An Organorhodium Tungsten Oxide Cluster with a Windmill-Like Skeleton: Synthesis of [(Cp*Rh)4W4O16] and Direct Observation by ESI-MS of an Unstable Intermediate [Cp*RhClWO4]....Pages 97-102
Role of Alkali-Metal Cation Size in Electron Transfer to Solvent-Separated 1:1 [(M+)(POM)] (M+=Li+, Na+, K+) Ion Pairs....Pages 103-127
New Classes of Functionalized Polyoxometalates: Organo-Nitrogen Derivatives of Lindqvist Systems....Pages 129-138
Polyoxometalate Speciation — Ionic Medium Dependence and Complexation to Medium Ions....Pages 139-147
Some Smaller Polyoxoanions. Their Synthesis and Characterization in Solution....Pages 149-155
Polyoxometalates: From Magnetic Models to Multifunctional Materials....Pages 157-168
Magnetic Exchange Coupling and Potent Antiviral Activity of [(VO)3(SbW9O33)2]12? ....Pages 169-180
Tetravanadate, Decavanadate, Keggin and Dawson Oxotungstates Inhibit Growth of S. cerevisiae ....Pages 181-195
Selective Oxidation of Hydrocarbons with Molecular Oxygen Catalyzed by Transition-Metal-Substituted Silicotungstates....Pages 197-203
Transition-Metal-Substituted Heteropoly Anions in Nonpolar Solvents — Structures and Interaction with Carbon Dioxide....Pages 205-215
Polyoxometalates and Solid State Reactions at Low Heating Temperatures....Pages 217-224
Structure Determination of Polyoxotungstates Using High-Energy Synchrotron Radiation....Pages 225-232
Back Matter....Pages 233-235

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The remarkable range of stoichiometries, structures, and acid-base and redox properties of the polyoxoanions of the early transition metals has lead to their use in areas as diverse as catalysis, imaging, and medicine. Recent progress in polyoxometalate chemistry has opened up the possibility of developing a nanotechnology via a bottom-up approach, starting from molecular (polyoxometalate) subunits which incorporate functionalities that are appropriate for electronic/magnetic devices, and other applications. This book provides an overview of recent progress in polyoxometalate chemistry from leading international research groups. Topics include the formation of large multi-subunit assemblies of polyoxometalates, and their functionalization, magnetic and electron-transfer properties, and biological interactions.
Content:
Front Matter....Pages i-viii
Chemistry with Nanoparticles: Linking of Ring-and Ball-Shaped Species....Pages 1-15
Prospects for Rational Assembly of Composite Polyoxometalates....Pages 17-26
Composite Materials Derived from Oxovanadium Sulfates....Pages 27-38
Solid State Coordination Chemistry: Bimetallic Organophosphonate Oxide Phases of the M/Cu/O/RPO3 2? Family (M=V, Mo)....Pages 39-57
Polyoxothiomolybdates Derived from the {Mo2O2S2(H2O)6}2+ Building Unit....Pages 59-71
Lanthanide Polyoxometalates: Building Blocks for New Materials....Pages 73-81
Dynamics of Organometallic Oxides: From Synthesis and Reactivity to DFT Calculations....Pages 83-95
An Organorhodium Tungsten Oxide Cluster with a Windmill-Like Skeleton: Synthesis of [(Cp*Rh)4W4O16] and Direct Observation by ESI-MS of an Unstable Intermediate [Cp*RhClWO4]....Pages 97-102
Role of Alkali-Metal Cation Size in Electron Transfer to Solvent-Separated 1:1 [(M+)(POM)] (M+=Li+, Na+, K+) Ion Pairs....Pages 103-127
New Classes of Functionalized Polyoxometalates: Organo-Nitrogen Derivatives of Lindqvist Systems....Pages 129-138
Polyoxometalate Speciation — Ionic Medium Dependence and Complexation to Medium Ions....Pages 139-147
Some Smaller Polyoxoanions. Their Synthesis and Characterization in Solution....Pages 149-155
Polyoxometalates: From Magnetic Models to Multifunctional Materials....Pages 157-168
Magnetic Exchange Coupling and Potent Antiviral Activity of [(VO)3(SbW9O33)2]12? ....Pages 169-180
Tetravanadate, Decavanadate, Keggin and Dawson Oxotungstates Inhibit Growth of S. cerevisiae ....Pages 181-195
Selective Oxidation of Hydrocarbons with Molecular Oxygen Catalyzed by Transition-Metal-Substituted Silicotungstates....Pages 197-203
Transition-Metal-Substituted Heteropoly Anions in Nonpolar Solvents — Structures and Interaction with Carbon Dioxide....Pages 205-215
Polyoxometalates and Solid State Reactions at Low Heating Temperatures....Pages 217-224
Structure Determination of Polyoxotungstates Using High-Energy Synchrotron Radiation....Pages 225-232
Back Matter....Pages 233-235
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