Ebook: Access in Nanoporous Materials

This series of books, which is published at the rate of about one per year, addresses fundamental problems in materials science. The contents cover a broad range of topics from small clusters of atoms to engineering materials and involve chemistry, physics, and engineering, with length scales ranging from Ångstromsup to millimeters. The emphasis is on basic science rather than on applications. Each book focuses on a single area ofcurrent interest and brings together leading experts to give an up-to-date discussion of their work and the work ofothers. Each article contains enough references that the interested reader can accesstherelevant literature. Thanks aregiven to the Center forFundamental Materials Research atMichigan State University forsupportingthis series. M.F. Thorpe, Series Editor E-mail: [email protected] EastLansing,Michigan, September, 1995 PREFACE This book records selected papers given at an interdisciplinary Symposium on Access in Nanoporous Materials held in Lansing, Michigan, on June 7-9, 1995. Broad interest in the synthesis of ordered materials with pore sizes in the 1.0-10 nm range was clearly manifested in the 64 invited and contributed papers presented by workers in the formal fields of chemistry, physics, and engineering. The intent of the symposium was to bring together a small number ofleading researchers within complementary disciplines to share in the diversity of approaches to nanoporous materials synthesis and characterization.

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Mesostructure: A New Family of Mesoporous Molecular Sieves; S.B.McCullen, et al. Recent Advances in Synthesis and Catalytic Applications of Mesoporous Molecular Sieves; P.T. Tanev, T.J.Pinnavaia. Synthesis of Surfactanttemplated Mesoporous Material from Homogenous Solutions; M.T. Anderson, et al.Carbon andLayered Materials: New Directions with Carbogenic Molecular Sieve Materials; H.C. Foley, et al. Layer Rigidity in Intercalation Compounds; S.A. Solin, M.F. Thorpe. Pillard Clays and Ion-exchanged Pillared Clays as Gas Adsorbents and as Catalysts for Selective Catalytic Reduction of NO; R.T. Yang, L.S. Cheng. Applications of Electrochemistry to the Study of Transport Phenomena in Layered Clays; A. Fitch.New Materials: Construction of Microporous Materials from Molecular Building Blocks; O.M.Yaghi. Solgel Processing of Amorphous Nanoporous Silicas: Thin Films and Bulk; C.J. Brinker, et al. Chemical and Electrochemical Reactions in Porous Solgel Materials; B.C. Dave, etal. Structure and Reversible Anion in Copper Hydroxy Double Salts; C.S. Bruschini, M.J. Hudson.Characterization of Zeolites andRelated Media: Structure-related Diffusion in Nanoporous Materials; J. K?rger. Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques; D.M.Ruthven. Critical Appraisal of the Pore Structure of MCM41; U.Ciesla et al.. Computer Modelling of Sorption in Zeolites; C.R.A. Catlow et al.. Characterization on Nanoporous Materials; M. Jaroniec. Electronic Structure Theory for Zeolites; A.A.Demkov, O.F. Sankey.Transport Processes: Pore Size, Permeability and Electrokinetic Phenemena; P. Wong, D.B. Pengra. A Molecular Simulaton Approach to Studying Mass Transfer across Surface Barriers; D.M. Ford, E.D. Glandt. Dynamics of Liquid Crystals Confined in Random Porous Matrices; F.M. Aliev. Nano and Microstructured Materials: The Role of the Interfaces in Tailoring Transport; L.A.Zook et al.. Diffusion and Magnetic Relaxation in Computergenerated Model Porous Media; A. Bhattacharya et al.. Quasielastic and Inelastic Neutron Scattering Studies of Layered Silicates; D.A.Neumann. Ionic and Electronic Tranport Properties of Layered Transition Metal Oxide/Conductive Polymer Nanocomposites; L.F.Nazar et al.. Index.

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Mesostructure: A New Family of Mesoporous Molecular Sieves; S.B.McCullen, et al. Recent Advances in Synthesis and Catalytic Applications of Mesoporous Molecular Sieves; P.T. Tanev, T.J.Pinnavaia. Synthesis of Surfactanttemplated Mesoporous Material from Homogenous Solutions; M.T. Anderson, et al.Carbon andLayered Materials: New Directions with Carbogenic Molecular Sieve Materials; H.C. Foley, et al. Layer Rigidity in Intercalation Compounds; S.A. Solin, M.F. Thorpe. Pillard Clays and Ion-exchanged Pillared Clays as Gas Adsorbents and as Catalysts for Selective Catalytic Reduction of NO; R.T. Yang, L.S. Cheng. Applications of Electrochemistry to the Study of Transport Phenomena in Layered Clays; A. Fitch.New Materials: Construction of Microporous Materials from Molecular Building Blocks; O.M.Yaghi. Solgel Processing of Amorphous Nanoporous Silicas: Thin Films and Bulk; C.J. Brinker, et al. Chemical and Electrochemical Reactions in Porous Solgel Materials; B.C. Dave, etal. Structure and Reversible Anion in Copper Hydroxy Double Salts; C.S. Bruschini, M.J. Hudson.Characterization of Zeolites andRelated Media: Structure-related Diffusion in Nanoporous Materials; J. K?rger. Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques; D.M.Ruthven. Critical Appraisal of the Pore Structure of MCM41; U.Ciesla et al.. Computer Modelling of Sorption in Zeolites; C.R.A. Catlow et al.. Characterization on Nanoporous Materials; M. Jaroniec. Electronic Structure Theory for Zeolites; A.A.Demkov, O.F. Sankey.Transport Processes: Pore Size, Permeability and Electrokinetic Phenemena; P. Wong, D.B. Pengra. A Molecular Simulaton Approach to Studying Mass Transfer across Surface Barriers; D.M. Ford, E.D. Glandt. Dynamics of Liquid Crystals Confined in Random Porous Matrices; F.M. Aliev. Nano and Microstructured Materials: The Role of the Interfaces in Tailoring Transport; L.A.Zook et al.. Diffusion and Magnetic Relaxation in Computergenerated Model Porous Media; A. Bhattacharya et al.. Quasielastic and Inelastic Neutron Scattering Studies of Layered Silicates; D.A.Neumann. Ionic and Electronic Tranport Properties of Layered Transition Metal Oxide/Conductive Polymer Nanocomposites; L.F.Nazar et al.. Index.
Content:
Front Matter....Pages i-xi
A New Family of Mesoporous Molecular Sieves....Pages 1-11
Recent Advances in Synthesis and Catalytic Applications of Mesoporous Molecular Sieves....Pages 13-27
Synthesis of Surfactant-Templated Mesoporous Materials from Homogeneous Solutions....Pages 29-37
New Directions with Carbogenic Molecular Sieve Materials....Pages 39-58
Layer Rigidity in Intercalation Compounds....Pages 59-71
Pillared Clays and Ion-Exchanged Pillared Clays as Gas Adsorbents and as Catalysts for Selective Catalytic Reduction of No....Pages 73-92
Applications of Electrochemistry to the Study of Transport Phenomena in Layered Clays....Pages 93-110
Construction of Microporous Materials from Molecular Building Blocks....Pages 111-121
Sol-Gel Processing of Amorphous Nanoporous Silicas: Thin Films and Bulk....Pages 123-139
Chemical and Electrochemical Reactions in Porous Sol-Gel Materials....Pages 141-159
Structure and Reversible Anion Exchange in Copper Hydroxy Double Salts....Pages 161-173
Structure-Related Diffusion in Nanoporous Materials....Pages 175-193
Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques....Pages 195-211
Structural Effects on the Adsorptive Properties of Molecular Sieves for Air Separation....Pages 213-229
Critical Appraisal of the Pore Structure of MCM-41....Pages 231-240
Computer Modelling of Sorption in Zeolites....Pages 241-254
Characterization of Nanoporous Materials....Pages 255-272
Electronic Structure Theory for Zeolites....Pages 273-294
Pore Size, Permeability and Electrokinetic Phenomena....Pages 295-317
A Molecular Simulation Approach to Studying Mass Transfer Across Surface Barriers....Pages 319-334
Dynamics of Liquid Crystals Confined in Random Porous Matrices....Pages 335-354
Nano- and Micro-Structured Materials:The Role of the Interfaces in Tailoring Transport....Pages 355-364
Diffusion and Magnetic Relaxation in Computer Generated Model Porous Media....Pages 365-379
Quasielastic and Inelastic Neutron Scattering Studies of Layered Silicates....Pages 381-404
Ionic and Electronic Transport Properties of Layered Transition Metal Oxide/Conductive Polymer Nanocomposites....Pages 405-427
Back Matter....Pages 429-441

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Mesostructure: A New Family of Mesoporous Molecular Sieves; S.B.McCullen, et al. Recent Advances in Synthesis and Catalytic Applications of Mesoporous Molecular Sieves; P.T. Tanev, T.J.Pinnavaia. Synthesis of Surfactanttemplated Mesoporous Material from Homogenous Solutions; M.T. Anderson, et al.Carbon andLayered Materials: New Directions with Carbogenic Molecular Sieve Materials; H.C. Foley, et al. Layer Rigidity in Intercalation Compounds; S.A. Solin, M.F. Thorpe. Pillard Clays and Ion-exchanged Pillared Clays as Gas Adsorbents and as Catalysts for Selective Catalytic Reduction of NO; R.T. Yang, L.S. Cheng. Applications of Electrochemistry to the Study of Transport Phenomena in Layered Clays; A. Fitch.New Materials: Construction of Microporous Materials from Molecular Building Blocks; O.M.Yaghi. Solgel Processing of Amorphous Nanoporous Silicas: Thin Films and Bulk; C.J. Brinker, et al. Chemical and Electrochemical Reactions in Porous Solgel Materials; B.C. Dave, etal. Structure and Reversible Anion in Copper Hydroxy Double Salts; C.S. Bruschini, M.J. Hudson.Characterization of Zeolites andRelated Media: Structure-related Diffusion in Nanoporous Materials; J. K?rger. Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques; D.M.Ruthven. Critical Appraisal of the Pore Structure of MCM41; U.Ciesla et al.. Computer Modelling of Sorption in Zeolites; C.R.A. Catlow et al.. Characterization on Nanoporous Materials; M. Jaroniec. Electronic Structure Theory for Zeolites; A.A.Demkov, O.F. Sankey.Transport Processes: Pore Size, Permeability and Electrokinetic Phenemena; P. Wong, D.B. Pengra. A Molecular Simulaton Approach to Studying Mass Transfer across Surface Barriers; D.M. Ford, E.D. Glandt. Dynamics of Liquid Crystals Confined in Random Porous Matrices; F.M. Aliev. Nano and Microstructured Materials: The Role of the Interfaces in Tailoring Transport; L.A.Zook et al.. Diffusion and Magnetic Relaxation in Computergenerated Model Porous Media; A. Bhattacharya et al.. Quasielastic and Inelastic Neutron Scattering Studies of Layered Silicates; D.A.Neumann. Ionic and Electronic Tranport Properties of Layered Transition Metal Oxide/Conductive Polymer Nanocomposites; L.F.Nazar et al.. Index.
Content:
Front Matter....Pages i-xi
A New Family of Mesoporous Molecular Sieves....Pages 1-11
Recent Advances in Synthesis and Catalytic Applications of Mesoporous Molecular Sieves....Pages 13-27
Synthesis of Surfactant-Templated Mesoporous Materials from Homogeneous Solutions....Pages 29-37
New Directions with Carbogenic Molecular Sieve Materials....Pages 39-58
Layer Rigidity in Intercalation Compounds....Pages 59-71
Pillared Clays and Ion-Exchanged Pillared Clays as Gas Adsorbents and as Catalysts for Selective Catalytic Reduction of No....Pages 73-92
Applications of Electrochemistry to the Study of Transport Phenomena in Layered Clays....Pages 93-110
Construction of Microporous Materials from Molecular Building Blocks....Pages 111-121
Sol-Gel Processing of Amorphous Nanoporous Silicas: Thin Films and Bulk....Pages 123-139
Chemical and Electrochemical Reactions in Porous Sol-Gel Materials....Pages 141-159
Structure and Reversible Anion Exchange in Copper Hydroxy Double Salts....Pages 161-173
Structure-Related Diffusion in Nanoporous Materials....Pages 175-193
Recent Progress in the Study of Intracrystalline Diffusion in Zeolites by Chromatographic and ZLC Techniques....Pages 195-211
Structural Effects on the Adsorptive Properties of Molecular Sieves for Air Separation....Pages 213-229
Critical Appraisal of the Pore Structure of MCM-41....Pages 231-240
Computer Modelling of Sorption in Zeolites....Pages 241-254
Characterization of Nanoporous Materials....Pages 255-272
Electronic Structure Theory for Zeolites....Pages 273-294
Pore Size, Permeability and Electrokinetic Phenomena....Pages 295-317
A Molecular Simulation Approach to Studying Mass Transfer Across Surface Barriers....Pages 319-334
Dynamics of Liquid Crystals Confined in Random Porous Matrices....Pages 335-354
Nano- and Micro-Structured Materials:The Role of the Interfaces in Tailoring Transport....Pages 355-364
Diffusion and Magnetic Relaxation in Computer Generated Model Porous Media....Pages 365-379
Quasielastic and Inelastic Neutron Scattering Studies of Layered Silicates....Pages 381-404
Ionic and Electronic Transport Properties of Layered Transition Metal Oxide/Conductive Polymer Nanocomposites....Pages 405-427
Back Matter....Pages 429-441
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