Ebook: Polyoxometalate Chemistry From Topology via Self-Assembly to Applications

An authoritative up-to-date summary of the chemistry and applications of polyoxometalates with emphasis on new synthetic strategies directed towards functionalized organic derivatives, self-assembly of mesoscopic composite polyoxoanions, generation of framework materials and thin oxide films, extended optical, magnetic, and electrical properties, applications in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological aspects of large symmetrical structures.

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An authoritative up-to-date summary of the chemistry and applications of polyoxometalates with emphasis on new synthetic strategies directed towards functionalized organic derivatives, self-assembly of mesoscopic composite polyoxoanions, generation of framework materials and thin oxide films, extended optical, magnetic, and electrical properties, applications in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological aspects of large symmetrical structures.
Content:
Front Matter....Pages i-vii
Introduction to Polyoxometalate Chemistry : From Topology via Self-assembly to Applications....Pages 1-6
Rational Approaches to Polyoxometalate Synthesis....Pages 7-22
Functionalization of Polyoxometalates : Achievements and Perspectives....Pages 23-38
From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M2O2S2]2+ Building Block M=Mo,W....Pages 39-53
Organometallic Oxometal Clusters....Pages 55-67
Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects....Pages 69-87
Syntheses and Crystal Structure Studies of Novel Selenium- and Tellurium-substituted Lacunary Polyoxometalates....Pages 89-99
Vibrational Spectroscopy of Heteropoly Acids....Pages 101-116
Bond-stretch Isomerism in Polyoxometalates?....Pages 117-133
Quantum-chemical studies of electron transfer in transition-metal substituted polyoxometalates....Pages 135-144
Aqueous Peroxoisopolyoxometalates....Pages 145-159
Molybdate speciation in systems related to the bleaching of kraft pulp....Pages 161-173
NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates....Pages 175-186
Molecular Aspect of Energy Transfer from Tb3+ to Eu3+ in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors....Pages 187-203
COnducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates....Pages 205-229
Molecular Materials from Polyoxometalates....Pages 231-253
Framework Materials Composed of Transition Metal Oxide Clusters....Pages 255-267
Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides....Pages 269-300
Polyoxometalate Clusters in a Supramolecular SelfOrganized Environment: Steps Towards Functional Nanodevices and Thin Film Applications....Pages 301-318
Polyoxometalate Chemistry: a Source for Unusual Spin Topologies....Pages 319-328
Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films....Pages 329-334
Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates....Pages 335-345
Aerobic Oxidations Catalyzed by Polyoxometalates....Pages 347-362
Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis....Pages 363-390
Ribosomal Crystallography and Heteropolytungstates....Pages 391-415
Photocatalytic Decontamination by Polyoxometalates....Pages 417-424
Back Matter....Pages 425-427

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An authoritative up-to-date summary of the chemistry and applications of polyoxometalates with emphasis on new synthetic strategies directed towards functionalized organic derivatives, self-assembly of mesoscopic composite polyoxoanions, generation of framework materials and thin oxide films, extended optical, magnetic, and electrical properties, applications in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological aspects of large symmetrical structures.
Content:
Front Matter....Pages i-vii
Introduction to Polyoxometalate Chemistry : From Topology via Self-assembly to Applications....Pages 1-6
Rational Approaches to Polyoxometalate Synthesis....Pages 7-22
Functionalization of Polyoxometalates : Achievements and Perspectives....Pages 23-38
From the First Sulfurated Keggin Anion to a New Class of Compounds Based on the [M2O2S2]2+ Building Block M=Mo,W....Pages 39-53
Organometallic Oxometal Clusters....Pages 55-67
Spherical (Icosahedral) Objects in Nature and Deliberately Constructable Molecular Keplerates: Structural and Topological Aspects....Pages 69-87
Syntheses and Crystal Structure Studies of Novel Selenium- and Tellurium-substituted Lacunary Polyoxometalates....Pages 89-99
Vibrational Spectroscopy of Heteropoly Acids....Pages 101-116
Bond-stretch Isomerism in Polyoxometalates?....Pages 117-133
Quantum-chemical studies of electron transfer in transition-metal substituted polyoxometalates....Pages 135-144
Aqueous Peroxoisopolyoxometalates....Pages 145-159
Molybdate speciation in systems related to the bleaching of kraft pulp....Pages 161-173
NMR Studies of Various Ligands Coordinated to Paramagnetic Polyoxometalates....Pages 175-186
Molecular Aspect of Energy Transfer from Tb3+ to Eu3+ in the Polyoxometalate Lattices: An Approach for Molecular Design of Rare-Earth Metal-Oxide Phosphors....Pages 187-203
COnducting and Magnetic Organic / Inorganic Molecular Materials Based on Polyoxometalates....Pages 205-229
Molecular Materials from Polyoxometalates....Pages 231-253
Framework Materials Composed of Transition Metal Oxide Clusters....Pages 255-267
Perspectives in the Solid State Coordination Chemistry of the Molybdenum Oxides....Pages 269-300
Polyoxometalate Clusters in a Supramolecular SelfOrganized Environment: Steps Towards Functional Nanodevices and Thin Film Applications....Pages 301-318
Polyoxometalate Chemistry: a Source for Unusual Spin Topologies....Pages 319-328
Heteropolyanions: Molecular Building Blocks for Ultrathin Oxide Films....Pages 329-334
Selective Oxidation of Hydrocarbons with Hydrogen Peroxide Catalyzed by Iron-substituted Silicotungstates....Pages 335-345
Aerobic Oxidations Catalyzed by Polyoxometalates....Pages 347-362
Polyoxoanions in Catalysis: From Record Catalytic Lifetime Nanocluster Catalysis to Record Catalytic Lifetime Catechol Dioxygenase Catalysis....Pages 363-390
Ribosomal Crystallography and Heteropolytungstates....Pages 391-415
Photocatalytic Decontamination by Polyoxometalates....Pages 417-424
Back Matter....Pages 425-427
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