Ebook: Advances in Organometallic Chemistry 53

Content: Cover -- Advances in Organometallic Chemistry -- Contents -- Contributors -- Metal Complexes of Monocarbon Carboranes: A Neglected Area of Study? -- Introduction -- Synthesis -- Triruthenium and Triosmium Complexes -- Mononuclear Compounds of Iron, Molybdenum, Tungsten, Rhenium, Platinum, Nickel and Cobalt -- Reactions -- Ruthenium and Osmium Cluster Compounds -- Mononuclear Metal Compounds -- Zwitterionic Bimetallic Compounds -- Monocarbollide-Metal Complexes with Non-Icosahedral Core Frameworks -- Chemistry of the 11-Vertex Dianions [1,1,1-(CO)3-2-Ph-closo-1,2-MCB9H9]2- (M = Mn, Re) -- Chemistry of the 11-Vertex Trianions [1,3,6-{M(CO)3}-3,6-(æ-H)2-1,1,1-(CO)3-2-Ph-closo-1,2-MCB9H7]3- (M = Mo, W) -- Acknowledgements -- References -- Synthesis of Novel Silicon-Containing Compounds via Lewis Acid-Catalyzed Reactions -- Introduction -- Allylsilylation Reactions with Allyltriorganosilanes -- Allylsilylation of Alkenes -- Allylsilylation of Alkynes -- Intramolecular Alkenyl-Migration Reaction of Alkenylchlorosilanes -- Friedel--Crafts Alkylation Reaction with Organosilicon Compounds -- Alkylation with Allylchlorosilanes -- Alkylation with Vinylchlorosilanes -- Alkylation with (?-Chloroalkyl)chlorosilanes -- Alkylation with (Polychloroalkyl)chlorosilanes -- Hydrosilylation Reaction with Triorganosilanes -- Acknowledgments -- References -- Bidentate Group 13 Lewis Acids with ortho-Phenylene and peri-Naphthalenediyl Backbones -- Introduction -- Synthesis -- Boron Polydentate Lewis Acids -- Aluminum, Gallium and Indium Polydentate Lewis Acids -- Interaction with Lewis Basic Substrates -- Complexation of Organic Substrates -- Complexation of Anions -- Conclusion -- Acknowledgments -- References -- Metallasilsesquioxanes -- Introduction -- Silsesquioxane Precursors -- Metallasilsesquioxanes -- Metallasilsesquioxanes of Main-Group Metals -- Metallasilsesquioxanes of the Early Transition Metals -- Metallasilsesquioxanes of the Middle and Late Transition Metals -- Future Outlook -- Acknowledgments -- References -- Cations of Group 14 Organometallics -- Introduction -- Synthetic Approaches to R3E+ Ions -- Heterolytic Cleavage of E-X Bonds -- Hydride Transfer Reaction -- Electrophilic Cleavage of E-Alkyl and E-Silyl Bonds -- Oxidative Cleavage of E- E and E-C Bonds -- Addition of Electrophiles to Heavy Carbenes -- Structure and Properties of R3E+ Cations -- Theoretical Considerations -- NMR Spectroscopic Properties of R3E+ Cations -- Miscellaneous Spectroscopic Data of R3E+ Cations -- Solid State Structure of R3E+ Cations and Related Species -- A chemistry of R3E+ cations -- Acknowledgements -- References -- Recent Advances in Nonclassical Interligand Si ... H Interactions -- Introduction -- Silane s-Complexes and Si--H ... M Agostic Complexes -- Silane s-Complexes. A Short Historical